PCB substances in the vicinity of Strážské, Slovakia

PCB substances (polychlorinated biphenyls) have been causing problems in the vicinity of the former chemical plant Chemko Strážske for several years. Originally they were considered completely harmless, but today they are among the 12 substances that the world community considers so dangerous that they should be eliminated from the ecosystem.

Similar to other industrialized countries, the environment was contaminated with PCB substances in Slovakia as a result of the long-term and relatively extensive industrial application of these substances (or their mixtures), even though the consequences of their entry into the ecosystems.
Contamination of the environment with these products has created a new significant group of solid PCB materials (contaminated soils, sands, sediments, or industrial wastes), the decontamination or disposal of which causes problems due to the persistence of PCBs against most destructive processes normally occurring in the ecosystem, e.g. photolytic and microbial (especially aerobic), especially in the case of higher chlorinated PCBs.
Directly in the plant, but also in its surroundings, there are still a lot of barrels with PCB substances, which, however, are already disintegrating and thus these substances get into the environment. They are carried by the water and blown by the wind to a wide area.

In 2021, we obtained a hen and eggs from a village near the plant, which we subjected to analysis to determine the value of PCB substances. The content of dioxin-related PCBs was 0.9505 pgTEQ/g fat in chicken and 1.241 pgTEQ/g fat in eggs. These values do not exceed the maximum PCB values defined by EU Commission Regulation No. 1259/2011. The amount of non-dioxin-like PCBs was determined in the hen at 53.123 ng/g fat and in the eggs even 70.950 ng/g fat, which exceeds the maximum PCB values defined by EU Commission Regulation No. 1259/2011 set at 40 ng/g fat.

In cooperation with scientists at the Slovak Technical University in Bratislava, we began to investigate the ability of humic substances to retain PCB substances. In this way, it would be possible to immobilize PCB substances in the soil and thus prevent their spread into the environment for a very long time. The first experiments showed a high ability of humic acids to capture PCB substances. For low-halogenated PCB substances, the decrease in the content of these substances in the tested solution was up to 10 times. However, more halogenated PCBs fell less. Since the more halogenated PCB substances are more dangerous and also accumulate more in the body, where they are degraded more poorly, we also started testing another sorbent that has a high affinity for these PCB substances. If the assumptions were confirmed, it would be possible to prepare a mixture directly intended for retaining PCB substances in the soil and preventing their penetration into the food chain.